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Because the game was a PlayStation 3 exclusive, it cannot run natively on the PPSSPP emulator. Here is a breakdown of why this link doesn't exist in the way many hope, and what your actual options are. The Technical Barrier
If you are looking for God of War titles specifically for the PPSSPP emulator, there are two critically acclaimed entries that were originally released for the PSP: God of War: Chains of Olympus (2008) God of War: Ghost of Sparta (2010) Discover God of War | PlayStation (US) god of war ascension ppsspp download link
The game is available for streaming through the PlayStation Plus Premium (Classics Catalog). Because the game was a PlayStation 3 exclusive,